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Metal-Air and Metal-Sulfur Batteries: Fundamentals and Applications (Electrochemical Energy Storage and Conversion)
by Vladimir Neburchilov and Jiujun ZhangMetal–air and metal–sulfur batteries (MABs/MSBs) represent one of the most efficient-energy storage technologies, with high round trip efficiency, a long life cycle, fast response at peak demand/supply of electricity, and decreased weight due to the use of atmospheric oxygen as one of the main reactants. This book presents an overview of the main MABs/MSBs from fundamentals to applications. Recent technological trends in their development are reviewed. It also offers a detailed analysis of these batteries at the material, component, and system levels, allowing the reader to evaluate the different approaches of their integration. The book provides a systematic overview of the components, design, and integration, and discusses current technologies, achievements, and challenges, as well as future directions. Each chapter focuses on a particular battery type including zinc–air batteries, lithium–air batteries, aluminum–air batteries, magnesium–air batteries, lithium–sulfur batteries, and vanadium–air redox flow batteries, and metal–sulfur batteries. Features the most recent advances made in metal–air/metal–sulfur batteries. Describes cutting-edge materials and technology for metal–air/metal–sulfur batteries. Includes both fundamentals and applications, which can be used to guide and promote materials as well as technology development for metal–air/metal–sulfur batteries. Provides a systematic overview of the components, design, and integration, and discusses current technologies, achievements, and challenges, as well as future directions. Covers a variety of battery types in depth, such as zinc–air batteries, lithium–air batteries, aluminum–air batteries, magnesium–air batteries, lithium–sulfur batteries, vanadium–air redox flow batteries, and metal–sulfur batteries.
Metal-Based Neurodegeneration
by Robert Crichton Roberta WardNeurodegenerative diseases of the human brain appear in various forms, resulting in disorders of movement and coordination, cognitive deterioration and psychiatric disturbances. Many of the key factors leading to neurodegenerative diseases are similar, including the dysfunction of metal ion homeostasis, redox-active metal ions generating oxidative stress, and intracellular inclusion bodies.Metal-based Neurodegeneration presents a detailed survey of the molecular origins of neurodegenerative diseases. Each chapter is dedicated to a specific disease, presenting the latest scientific findings, including details of their biochemical actors (proteins or peptides), their normal and pathological conformations, and a description of the diseases characteristics, with an emphasis on the role of metal-induced oxidative stress, which can result in the production of intracellular aggregates of target proteins and peptides. Topics covered include:Brain function, physiology and the blood-brain barrierImmune system and neuroinflammationAging and mild cognitive impairment, MCIParkinson's DiseaseAlzheimer's DiseaseCreutzfelt-Jakob and related prion diseasesAlcoholic Brain DamageTherapeutic strategies to combat the onset and progression of neurological diseasesThis extensively updated, full colour, second edition of Metal-based Neurodegeneration is an essential text for research scientists and clinicians working in gerontology, neuropathology, neurochemistry, and metalloprotein mechanisms.
Metal-Catalyzed Polymerization: Fundamentals to Applications
by Samir H. Chikkali, Ashootosh V. Ambade, Bas de Bruin and Michael ShaverThe proposed book focusses on metal mediated/catalyzed “controlled/living radical polymerization” (CRP/LRP) methods. It surveys a wide variety of catalyzed polymerization reactions, making it essentially a “one stop” review in the field. A significant contribution to polymer science is “metathesis polymerization” discovered by Grubbs and others. The book will cover various metathesis polymerization methods and implications in polymer industry.
Metal-Containing Molecules and Nanomaterials: From Diagnosis to Therapy (ISSN)
by Astrid Sigel Helmut Sigel Eva Freisinger Bettencourt-Dias, Ana de Sigel, Roland K. O.Since the discovery and successful deployment of salvarsan to treat syphilis, as well as cisplatin as a cancer drug, the field of metallodrugs has been flourishing. In addition to therapeutic applications, metals and metal-containing molecules have properties, such as an electrochemical or an optical signal, that can be used to diagnose biologically relevant molecules or unravel cellular metabolism. Moreover, metals are part of the essential elements for life, and of increased attention in nutraceuticals. Most of the current diagnosis processes, therapeutics, and nutraceuticals are based on organic molecules. MILS-26 reviews in 7 comprehensive chapters, written by 20 experienced authors, the most recent metal-containing molecules and nanomaterials for diagnosis and therapy.Features: The field of metallodrugs has been flourishing and this area of research can be used to diagnose specific biologically relevant molecules or unravel cellular metabolism. The authors are preeminent bioinorganic and medicinal inorganic chemists and review the most current research in this field. The book discusses the properties and therapeutic applications of metals and metal-containing molecules including the use of electrochemical or optical signal for diagnosis of biologically relevant molecules. It endorses and stimulates research in the vibrant field of biological inorganic chemistry. It reviews the most current research supporting the relevance of metal-containing molecules and nanomaterials for diagnosis and therapy.
Metal-Dielectric Interfaces in Gigascale Electronics
by Toh-Ming Lu Ming HeMetal-dielectric interfaces are ubiquitous in modern electronics. As advanced gigascale electronic devices continue to shrink, the stability of these interfaces is becoming an increasingly important issue that has a profound impact on the operational reliability of these devices. In this book, the authors present the basic science underlying the thermal and electrical stability of metal-dielectric interfaces and its relationship to the operation of advanced interconnect systems in gigascale electronics. Interface phenomena, including chemical reactions between metals and dielectrics, metallic-atom diffusion, and ion drift, are discussed based on fundamental physical and chemical principles. Schematic diagrams are provided throughout the book to illustrate interface phenomena and the principles that govern them. Metal-Dielectric Interfaces in Gigascale Electronics provides a unifying approach to the diverse and sometimes contradictory test results that are reported in the literature on metal-dielectric interfaces. The goal is to provide readers with a clear account of the relationship between interface science and its applications in interconnect structures. The material presented here will also be of interest to those engaged in field-effect transistor and memristor device research, as well as university researchers and industrial scientists working in the areas of electronic materials processing, semiconductor manufacturing, memory chips, and IC design.
Metal-Fluorocarbon Based Energetic Materials
by Ernst-Christian KochMetal-Fluorocarbon Based Energetic Materials This exciting new book details all aspects of a major class of pyrolants and elucidates the progress that has been made in the field, covering both the chemistry and applications of these compounds. Written by a pre-eminent authority on the subject from the NATO Munitions Safety Information Analysis Center (MSIAC), it begins with a historical overview of the development of these materials, followed by a thorough discussion of their ignition, combustion and radiative properties. The next section explores the multiple facets of their military and civilian applications, as well as industrial synthetic techniques. The critical importance of the associated hazards, namely sensitivity, stability and aging, are discussed in detail, and the book is rounded off by an examination of the future of this vital and expanding field.The result is a complete guide to the chemistry, manufacture, applications and required safety precautions of pyrolants for both the military and chemical industries.From the preface:“... This book fills a void in the collection of pyrotechnic literature... it will make an excellent reference book that all researchers of pyrolants and energetics must have...” Dr. Bernard E. Douda, Dr. Sara Pliskin, NAVSEA Crane, IN, USA
Metal-Halide Perovskite Semiconductors: From Physical Properties to Opto-electronic Devices and X-ray Sensors
by Krzysztof Kris Iniewski Wanyi NieThis book will provide readers with a good overview of some of most recent advances in the field of technology for perovskite materials. There will be a good mixture of general chapters in both technology and applications in opto-electronics, Xray detection and emerging transistor structures. The book will have an in-depth review of the research topics from world-leading specialists in the field. The authors build connections between the materials’ physical properties to the main applications such as photovoltaics, LED, FETs and X-ray sensors. They also discuss the similarities and main differences when using perovskites for those devices.
Metal-Ion Hybrid Capacitors for Energy Storage: A Balancing Strategy Toward Energy-Power Density (SpringerBriefs in Energy)
by Satyajit Ratha Aneeya Kumar SamantaraRapid growth in the research and development of clean energy storage techniques has yielded a significant number of electrochemically active compounds/materials possessing enormous potential to facilitate the fabrication of next generation devices such as the supercapacitor. This Brief describes recent progress in the field of metal-ion based hybrid electrical energy storage devices, with emphasis on the effect of different metal ions and other constituent components on the overall electrochemical performance of battery-supercapacitor hybrids (BSHs). Although significant efforts have been made to create an effective electrical energy storage system that would have the energy density of a battery and the power density of a supercapacitor, persistent challenges still lie in combining these two altogether different systems to form a cost-effective and safe storage device. Detailed comparisons of output performance and longevity (in terms of cyclic stability) are provided, including device fabrication cost and safety.Of the several proposed schematics/prototypes, hybrid supercapacitors, with both carbon-based EDLC electrode and pure faradic (battery type) electrode can work in tandem to yield high energy densities with little degradation in specific power. As a promising electric energy storage device, supercapacitors address several critical issues in various fields of applications from miniaturized electronic devices and wearable electronics to power hungry heavy automobiles. Depending on the electrode configuration and other controlling parameters, these BSHs can have contrasting performance statistics. Metal ion BSHs such as Li+, Na+, Mg+2, Zn+2 etc., acid-alkaline BSHs, and redox electrolyte based BSHs all represent recent approaches, with BSHs based on metal ions, particularly Lithium, of particular interest because of the extreme popularity of Li-ion based batteries. This book is written for a broad readership of graduate students and academic and industrial researchers who are concerned with the growth and development of sustainable energy systems where efficient and cost-effective storage is key.
Metal-Ligand Co-operativity: Catalysis and the Pincer-Metal Platform (Topics in Organometallic Chemistry #68)
by Gerard Van Koten Marc-Etienne Moret Karl KirchnerThis book provides researchers in the fields of organic chemistry, organometallic chemistry and homogeneous catalysis with an overview of significant recent developments in the area of metal-ligand cooperativity, with a focus on pincer architectures. The various contributions highlight the widespread impact of M–L co-operativity phenomena on modern organometallic chemistry and catalyst development. The development of efficient and selective catalytic transformations relies on the understanding and fine control of the various elementary reactions that constitutes a catalytic cycle. Co-operative ligands, which actively participate in bond making and bond breaking together to the metal they support, open up new avenues in this area. In particular, buttressing a weak or reactive metal-ligand bond by flanking coordinating arms in a pincer ligand design is proving a versatile strategy to access robust metal complexes that exhibit unusual and selective reactivity patterns.
Metal-Matrix Composites: Advances in Analysis, Measurement, and Observations (The Minerals, Metals & Materials Series)
by T. S. Srivatsan W. C. Harrigan Jr. Simona Hunyadi MurphThis collection brings together engineers, scientists, scholars, and entrepreneurs to present their novel and innovative contributions in the domain specific to metal-matrix composites and on aspects specific to modeling, analysis, measurements, and observations specific to microstructural advances. Topics include but are not limited to: · Metals and metal-matrix composites · Nano-metal based composites · Intermetallic-based composites Contributions in the above topics connect to applications in industry-relevant areas: automotive, energy applications, aerospace, failure analysis, biomedical and healthcare, and heavy equipment and machinery.
Metal-Matrix Composites: Advances in Processing, Characterization, Performance and Analysis (The Minerals, Metals & Materials Series)
by Pradeep K. Rohatgi T. S. Srivatsan Simona Hunyadi MurphThis collection brings together engineers, scientists, scholars, and entrepreneurs to present their novel and innovative contributions in the domain specific to metal-matrix composites and on aspects specific to processing, characterization, mechanical behavior, measurements, failure behavior, and kinetics governing microstructural influences on failure by fracture. Topics include but are not limited to: • Metals and metal-matrix composites • Nano-metal based composites • Intermetallic-based composites Contributions in the above topics connect to applications in industry-relevant areas: automotive; nuclear and clean energy; aerospace; failure analysis; biomedical and healthcare; and heavy equipment, machinery, and goods.
Metal-Metal Bonding
by Gerard ParkinJohn Berry: Metal-Metal Bonds in Chains of Three or More Metal Atoms: From Homometallic to Heterometallic Chains.- Malcolm Chisholm: Electronically Coupled MM Quadruple Bonded Complexes of Molybdenum and Tungsten.- Philip Power: Transition Metal Complexes Stabilized by Bulky Terphenyl Ligands: Applications to Metal-Metal Bonded Compounds.- Gerard Parkin: Metal-Metal Bonding in Bridging Hydride and Alkyl Compounds.- Roland Fischer and Gernot Frenking: Structure and Bonding of Metal Rich Coordination Compounds Containing Low Valent Ga(I) and Zn(I) Ligands.- Mike Hill: Homocatenation of Metal and Metalloid Main Group Elements.- Constandinos A. Tsipis: Aromaticity/Antiaromaticity in "Bare" and ''Ligand-Stabilized'' Rings of Metal Atoms.- Alexander Boldyrev: All-Transition Metal Aromaticity and Antiaromaticity.
Metal-Organic Framework Materials
by Leonard R. Macgillivray Charles M. LukehartMetal-Organic Frameworks (MOFs) are crystalline compounds consisting of rigid organic molecules held together and organized by metal ions or clusters. Special interests in these materials arise from the fact that many are highly porous and can be used for storage of small molecules, for example H2 or CO2. Consequently, the materials are ideal candidates for a wide range of applications including gas storage, separation technologies and catalysis. Potential applications include the storage of hydrogen for fuel-cell cars, and the removal and storage of carbon dioxide in sustainable technical processes. MOFs offer the inorganic chemist and materials scientist a wide range of new synthetic possibilities and open the doors to new and exciting basic research. Metal-Organic Frameworks Materials provides a solid basis for the understanding of MOFs and insights into new inorganic materials structures and properties. The volume also reflects progress that has been made in recent years, presenting a wide range of new applications including state-of-the art developments in the promising technology for alternative fuels. The comprehensive volume investigates structures, symmetry, supramolecular chemistry, surface engineering, recognition, properties, and reactions. The content from this book will be added online to the Encyclopedia of Inorganic and Bioinorganic Chemistry: http://www.wileyonlinelibrary.com/ref/eibc
Metal-Organic Framework Nanocomposites: From Design to Application
by Anish Khan, Mohammad Jawaid, Abdullah Mohammed Ahmed Asiri, Wei Ni, and Mohammed Muzibur RahmanMetal-Organic Framework Nanocomposites: From Design to Application assembles the latest advances in MOF nanocomposites, emphasizing their design, characterization, manufacturing, and application and offering a wide-ranging view of these materials with exceptional physical and chemical properties. FEATURES Discusses various types of MOF materials, such as polyaniline MOF nanocomposites, magnetic MOF nanocomposites, and carbon nanotube-based MOF nanocomposites Includes chapters on the usage of these materials in pollutant removal, electrochemical devices, photocatalysts, biomedical applications, and other applications Covers different aspects of composite fabrication from energy storage and catalysts, including preparation, design, and characterization techniques Emphasizes the latest technology in the field of manufacturing and design Aimed at researchers, academics, and advanced students in materials science and engineering, this book offers a comprehensive overview and analysis of these extraordinary materials.
Metal-Organic Frameworks (MOFs) as Catalysts
by Shikha GulatiThis book highlights the state-of-the-art research and discovery in the use of MOFs in catalysis, highlighting the scope to which these novel materials have been incorporated by the community. It provides an exceptional insight into the strategies for the synthesis and functionalization of MOFs, their use as CO2 and chemical warfare agents capture, their role in bio-catalysis and applications in photocatalysis, asymmetric catalysis, nano-catalysis, etc. This book will also emphasize the challenges with previous signs of progress and way for further research, details relating to the current pioneering technology, and future perspectives with a multidisciplinary approach. Furthermore, it presents up-to-date information on the economics, toxicity, and regulations related to these novel materials.
Metal-Organic Frameworks as Forensic Detectors
by Vivek Mishra Amarnath MishraThis book illustrates the application of Metal-Organic Frameworks (MOFs) based detectors and scientific methods in the Forensic sciences. The introductory chapter provides metal-organic frameworks as materials for applications in sensors and reviews their photochemical and electrochemical properties. The subsequent chapter probes the interaction between Metal-Organic Frameworks and forensic samples. Further, the chapters discuss the applications of the metal-organic framework for the detection of fingerprint latent, lip-print, palm-print, pesticides, and antibiotics in forensic samples. Further, the chapters review the use of metal-organic frameworks for the detection of drugs of abuse, explosives, hazardous chemicals, and gunshots residual. Towards the end, the chapter reviews the advantages and disadvantages of MOFs during forensic sample detection and current challenges and prospects. This book provides useful information on applications of metal-organic Frameworks for forensic scientists and legal professionals.
Metal-Organic Frameworks for Photonics Applications
by Banglin Chen Guodong QianThe series Structure and Bonding publishes critical reviews on topics of research concerned with chemical structure and bonding. The scope of the series spans the entire Periodic Table and addresses structure and bonding issues associated with all of the elements. It also focuses attention on new and developing areas of modern structural and theoretical chemistry such as nanostructures, molecular electronics, designed molecular solids, surfaces, metal clusters and supramolecular structures. Physical and spectroscopic techniques used to determine, examine and model structures fall within the purview of Structure and Bonding to the extent that the focus is on the scientific results obtained and not on specialist information concerning the techniques themselves. Issues associated with the development of bonding models and generalizations that illuminate the reactivity pathways and rates of chemical processes are also relevant. The individual volumes in the series are thematic. The goal of each volume is to give the reader, whether at a university or in industry, a comprehensive overview of an area where new insights are emerging that are of interest to a larger scientific audience. Thus each review within the volume critically surveys one aspect of that topic and places it within the context of the volume as a whole. The most significant developments of the last 5 to 10 years should be presented using selected examples to illustrate the principles discussed. A description of the physical basis of the experimental techniques that have been used to provide the primary data may also be appropriate, if it has not been covered in detail elsewhere. The coverage need not be exhaustive in data, but should rather be conceptual, concentrating on the new principles being developed that will allow the reader, who is not a specialist in the area covered, to understand the data presented. Discussion of possible future research directions in the area is welcomed. Review articles for the individual volumes are invited by the volume editors. Readership: research scientists at universities or in industry, graduate students Special offer For all customers who have a standing order to the print version of Structure and Bonding, we offer free access to the electronic volumes of the Series published in the current year via SpringerLink.
Metal-Organic Frameworks in Biomedical and Environmental Field
by Patricia Horcajada Cortés Sara Rojas MacíasThis book joins an international and interdisciplinary group of leading experts on the biomedical, energy and environmental applications of Metal-Organic Frameworks (MOFs). The resulting overview covers everything from the environmentally friendly and scale up synthesis of MOFs, their application in green energy generation and storage, and water purification to their use as drug delivery systems, biosensors, and their association with relevant macromolecules (genes, enzymes). This book is focused on the interest of MOFs in applications such as the leading –edge environmental (energy-related) and biomedical fields. The potential of MOFs in these areas is currently progressing at a fast pace, since the wide possibilities that MOFs offer in terms of composition, topology, incorporation of active species (in their porosity, on their external surface or within the framework), and post-synthetic modifications, among others. The aim here is to provide future research goals that emphasize relevant nuances to this class of materials as a whole.
Metal-Organic Frameworks with Heterogeneous Structures
by Ali Morsali Kayhaneh BerijaniFor the first time, in this book, a new view of metal-organic frameworks (MOFs) has been presented: MOFs with heterogeneous structures. In this field, there are different levels of understanding we need to consider. So, the principal aspects of heterogeneity that produce complexity in MOFs, their effects in the structure chemistry, performance and applications have been thoroughly reported. According to that there is no book that covers whole of the aspects of complexity in MOFs with heterogeneous structures, our findings can be as essential concepts with introducing complexity to design the new platforms of materials with advanced and better properties in the future.
Metal-Organic Frameworks-Based Hybrid Materials for Environmental Sensing and Monitoring
by Ram K. GuptaWith an unprecedented population boom and rapid industrial development, environmental pollution has become a severe problem for the ecosystem and public health. Classical techniques for sensing and determining environmental contaminants often require complex pretreatments, expensive equipment, and longer testing times. Therefore, new, and state-of-the-art sensing technologies possessing the advantages of excellent sensitivity, rapid detection, ease of use, and suitability for in situ, real-time, and continuous monitoring of environmental pollutants, are highly desirable. Metal-Organic Frameworks-based Hybrid Materials for Environmental Sensing and Monitoring covers the current-state-of-the-art hybrid nanomaterials based on metal-organic frameworks for electrochemical monitoring purposes. Accomplished authors cover various synthetic routes, methods, and theories behind enhancing the electrochemical properties and applications of metal-organic frameworks-based hybrid nanomaterials for electrochemical sensing of environmental pollutants under one roof. This book is essential reading for all academic and industrial researchers working in the fields of materials science and nanotechnology.
Metal-Organic Frameworks: Applications from Catalysis to Gas Storage
by David FarrussengAn international and interdisciplinary team of leading experts from both academia and industry report on the wide range of hot applications for MOFs, discussing both the advantages and limits of the material. The resulting overview covers everything from catalysis, H2 and CH4 storage and gas purification to drug delivery and sensors. From the Contents: - Design of Porous Coordination Polymers/Metal-Organic Frameworks: Past, Present and Future - Design of Functional Metal-Organic Frameworks by Post-Synthetic Modification - Thermodynamic Methods for Prediction of Gas Separation in Flexible Frameworks - Separation and purification of gases by MOFs - Opportunities for MOFs in CO2 capture from flue gases, natural gas and syngas by adsorption - Manufacture of MOF thin films on structured supports for separation and catalysis - Research status of Metal-Organic Frameworks for on-board cryo-adsorptive hydrogen storage applications - Separation of xylene isomers - Metal-Organic Frameworks as Catalysts for Organic Reactions - Biomedical applications of Metal Organic Frameworks - Metal Organic Frameworks for Biomedical Imaging - Luminescent Metal-Organic Frameworks - Deposition of thin films for sensor applications - Industrial MOF Synthesis - MOF shaping and immobilisation A must-have for every scientist in the field.
Metal-Organic Frameworks: Applications in Separations and Catalysis
by Hermenegildo García Sergio NavalónFocusing on applications in separation, adsorption and catalysis, this handbook underlines the importance of this hot and exciting topic. It provides an excellent insight into the synthesis and modification of MOFs, their synthesis on an industrial scale, their use as CO2 and chemical warfare adsorbers, and the role of defects in catalysis. In addition, the authors treat such new aspects as biocatalysis and applications in photocatalysis and optoelectronic devices.
Metal-Organic Frameworks: Design and Application (Eic Bks.)
by Leonard R. MacGillivrayMetal-organic frameworks represent a new class of materials that may solve the hydrogen storage problem associated with hydrogen-fueled vehicles. In this first definitive guide to metal-organic framework chemistry, author L. MacGillivray addresses state-of-art developments in this promising technology for alternative fuels. Providing professors, graduate and undergraduate students, structural chemists, physical chemists, and chemical engineers with a historical perspective, as well as the most up-to-date developments by leading experts, Metal-Organic Frameworks examines structure, symmetry, supramolecular chemistry, surface engineering, metal-organometallic frameworks, properties, and reactions.
Metal-Responsive Base Pair Switching of Ligand-type Uracil Nucleobases (Springer Theses)
by Keita MoriIn this thesis, the author proposes "metal-responsive base pair switching" of ligand-modified nucleobases as a novel tool for stimuli-responsive control of DNA assemblies. It is written to demonstrate broad applicability of the base pair switching in dynamic DNA nanotechnology and inspire researchers to use this technique. Based on specific interactions between ligand-type nucleobases and target metal ions, in this volume, DNA hybridization was dynamically controlled through strand displacement reactions. The base pair switching was further applied to develop metal-dependent DNA molecular machines. This novel strategy for stimuli-responsive regulation of DNA assemblies will greatly expand the scope of dynamic DNA nanotechnology. This volume uniquely features importance of elaborate molecular design based on chemistry for imparting stimuli responsiveness to DNA assemblies.
Metalation of Azines and Diazines
by Marko D. Mihovilovic Michael SchnürchReactions of Pyridines, Benzopyridines and Azapyridines with Organomagnesiums and Organolithiums, by Manfred Schlosser Lithiations and Magnesiations on Quinoline and Isoquinoline, by Floris Chevallier, Florence Mongin Metalation Reactions of Pyridines, Quinolines, and Isoquinolines with Ate Bases and Their Alkali Metal Salt-Modified Congeners, by Costa Metallinos, Kathryn Stromski Lithiations and Grignard Reactions on Pyrimidine and Quinazoline, by Andrej Kolarovic Other Stoichiometric Metalation Reactions on Pyrimidine and Quinazoline, by Philippe C. Gros Metalation of Pyrazine and Quinoxaline, by Nelly Plé1, Corinne Fruit Metalation of Pyridazine, Cinnoline, and Phtalazine, by Ernst Horkel