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Metallic Nanoparticles for Health and the Environment (Advances in Bionanotechnology)
by Md Sabir Alam Md Noushad Javed Jamilur R. AnsariMetallic Nanoparticles for Health and the Environment covers different routes of synthesis for metallic nanoparticles and their process variables. Both the functions and roles of these particles as a drug delivery system and diagnostic agent and other potential theranostic purposes against metabolic disorders, photocatalysis applications, as well as wastewater treatments, are discussed. The book compares the different properties of bulk metallic forms and their nanoparticulated forms. It discusses the mechanisms and impacts of different process variables in different synthesis routes, as well as emerging trends in clinics and so forth. Features: Covers different routes of synthesis to create metallic nanoparticles (MNPs) of different characteristics with reference to bulk forms of metals. Describes formulation parameters that have a significant effect on these MNPs including dimensions, morphology, mechanism, surface properties, and other characteristics. Discusses different roles and performances of MNPs in photothermal therapy, metabolic disorders, mechanisms in bacterial, fungal, and viral infections, and inflammatory pathways. Reviews the potential and emerging roles of different MNPs with site target delivery applications and genetic manipulation purposes. Examines the advantages and challenges of these MNPs against remediation of pollutants and toxicants, owing to their superior surface catalytic activities. This book is aimed at researchers and professionals in nanomaterials, pharmaceuticals, and drug delivery.
Metallic Powders for Additive Manufacturing: Science and Applications
by James F. Shackelford Kaka Ma Enrique J. Lavernia Julie M. Schoenung Baolong ZhengMetallic Powders for Additive Manufacturing Overview of successful pathways for producing metal powders for additive manufacturing of high-performance metallic parts and components with tailored properties Metallic Powders for Additive Manufacturing introduces the readers to the science and technology of atomized metal powders beyond empirical knowledge and the fundamental relationships among the chemistry, microstructure, and morphology of atomized metallic powders and their behavior during additive manufacturing. The text sets a foundation of the underlying science that controls the formation and microstructure of atomized metallic droplets, including the relations among the properties of metallic powders, their performance during the manufacturing processes, and the resulting products. Other topics covered include the influence of powder on defect formation, residual stress, mechanical behavior, and physical properties. The concluding two chapters encompass considerations of broader societal implications and overarching themes, including the exploration of alternative feedstock materials, economic analysis, and sustainability assessment. These chapters offer valuable perspectives on the prospective trajectory of the field. Written by a team of experienced and highly qualified professors and academics, Metallic Powders for Additive Manufacturing includes information on: Atomization techniques such as Vacuum Induction Gas Atomization (VIGA), Electrode Induction Melting Gas Atomization (EIMGA), and Plasma Rotating Electrode Process (PREP) Atomization science and technology, covering control of atomization parameters, powder size distribution, effect of processing variables, and theoretical models of atomization Heat transfer and solidification of droplets, covering nucleation, microstructure development, and important thermal and solidification conditions during atomization Atomization of Al, Fe, Ni, Co, Ti, and high entropy alloys, as well as composite powders for additive manufacturing, and guidelines for atomization equipment and powder handling Fundamental processing principles in a variety of metal additive manufacturing processes Powder characteristics and requirements for different additive manufacturing processes Effect of powder chemistry and physical characteristics on additive manufacturing processes, and the microstructure and properties of the built parts Evaluation of alternative feedstock sources for metal additive manufacturing, beyond gas atomized powder Economic and sustainability perspectives on powder production and additive manufacturing Metallic Powders for Additive Manufacturing is an excellent combination of rigorous fundamentals and a practice-oriented and forward-looking resource on the subject for materials scientists and practicing engineers seeking to understand, optimize, and further develop the field of powder production and additive manufacturing.
Metallic Spintronic Devices (Devices, Circuits, and Systems #32)
by Krzysztof Iniewski Xiaobin WangMetallic Spintronic Devices provides a balanced view of the present state of the art of metallic spintronic devices, addressing both mainstream and emerging applications from magnetic tunneling junction sensors and spin torque oscillators to spin torque memory and logic. Featuring contributions from well-known and respected industrial and academic experts, this cutting-edge work not only presents the latest research and developments but also: Describes spintronic applications in current and future magnetic recording devices Discusses spin-transfer torque magnetoresistive random-access memory (STT-MRAM) device architectures and modeling Explores prospects of STT-MRAM scaling, such as detailed multilevel cell structure analysis Investigates spintronic device write and read optimization in light of spintronic memristive effects Considers spintronic research directions based on yttrium iron garnet thin films, including spin pumping, magnetic proximity, spin hall, and spin Seebeck effects Proposes unique solutions for low-power spintronic device applications where memory is closely integrated with logic Metallic Spintronic Devices aims to equip anyone who is serious about metallic spintronic devices with up-to-date design, modeling, and processing knowledge. It can be used either by an expert in the field or a graduate student in course curriculum.
Metallic Systems: A Quantum Chemist's Perspective
by Thomas C. Allison Orkid Coskuner Carlos A. GonzálezMetallic systems are ubiquitous in daily life. They play key roles, for example, in the chemistry of many biomolecules, ionic solutions, nanoparticles, and catalytic processes. They may be in solid, liquid, or gaseous form. The interactions of other molecules with metal surfaces are of considerable importance. Each of these topics is addressed in M
Metallized Plastics 5&6: Fundamental and Applied Aspects
by K. L. MittalThis book chronicles the proceedings of the 5th and 6th symposia on Metallized Plastics: Fundamental and Applied Aspects, held in May 1996 and September 1997 respectively. This volume contains 29, carefully reviewed, revised and up-dated papers which were presented at both symposia. The book is divided in the following three parts: Metallization Te
Metallized Plastics 7: Fundamental and Applied Aspects
by K. L. MittalThis volume documents the proceedings of the 7th Symposium on Metallized Plastics: Fundamental and Applied Aspects, held in Newark, New Jersey, December 2-3, 1999. This volume contains a total of 16 papers, which were all rigorously peer reviewed and suitably revised before inclusion. The book is divided into two parts: Metallization Techniques and Properties of Metal Deposits, and Interfacial and Adhesion Aspects. The topics covered include: various metallization techniques for a variety of plastics including some novel developments involving suitable plastic pretreatments; modification of polymers by plasma and ion-assisted reactions; metal doped plasma polymer films; metal-polyimide nanocomposite films; investigation of metal/polymer interactions by a variety of techniques; ways to improve adhesion of metal/polymer systems; modeling of metal/polymer interfaces; application of surface analytical techniques in the arena of metallized plastics; and ultrathin films on metal surfaces. This volume offers a wealth of information and represents current commentary on the R&D activity taking place in the technologically highly important field of metallized plastics and is of value and interest to anyone interested in the fundamental or applied aspects of metallized plastics.
Metallized and Magnetic Polymers
by Johannes Karl FinkThis book focuses on the chemistry of metallized and magnetic polymers, as well as the special applications of these materials. After an introductory section on the general aspects of the field, the types and uses of these polymers are detailed, followed by an overview of the testing methods. The book is divided equally into two parts - metallized polymers and magnetic polymers - and both parts follow the same structure: All methods of fabrication Properties and methods of measurement including standard test methods and interface properties Fields of applications Environmental issues including recycling and biodegradable polymers
Metallo-Supramolecular Polymers: Synthesis, Properties, and Device Applications (NIMS Monographs)
by Masayoshi HiguchiThis book introduces the synthesis, electrochemical and photochemical properties, and device applications of metallo-supramolecular polymers, new kinds of polymers synthesized by the complexation of metal ions and organic ditopic ligands. Their electrochemical and photochemical properties are also interesting and much different from conventional organic polymers. The properties come from the electronic intra-chain interaction between the metal ions and the ligands in the polymer chain. In this book, for example, the electrochromism that the Fe(II)-based metallo-supramolecular polymer exhibits is described: the blue color of the polymer film disappears by the electrochemical oxidation of Fe(II) ions to Fe(III) and the colorless film becomes blue again by the electrochemical reduction of Fe(III) to Fe(II). The electrochromism is explained by the disappearance/appearance of the metal-to-ligand charge transfer absorption. The electrochromic properties are applicable to display devices such as electronic paper and smart windows.
Metallocenes in Regio- and Stereoselective Synthesis (Topics in Organometallic Chemistry #74)
by Marko Hapke Martin KotoraThis book presents the latest synthetic protocols for the assembly of functionalized Cp ligands and their transition metal complexes. Cyclopentadienyl (Cp) complexes of transition metals belong to the most important classes of transition metal complexes with tightly bound ligands in the coordination sphere since their discovery in the middle of the last century. Even though they have been known for a long time, this field constantly evolves to deliver novel modified Cp ligands and complexes and to blossom into new fields of application. Beside the synthesis of ligands and metal complexes this book concentrates on novel and prospering fields of their application in organic synthesis. In this respect the Cp complexes have been applied to induce and catalyze various significant chemical transformations such as new C-C bond formation involving unsaturated substrates (e.g. cyclotrimerizations, cycloadditions, carbometallations, etc.), C-H bond and C-C bond activations followed by subsequent reactions (e.g. arylation, alkenylations, annulations, etc.), as well as many other processes. This volume also covers the recent development and application of chiral Cp complexes in enantioselective synthesis.
Metallocofactors that Activate Small Molecules: With Focus on Bioinorganic Chemistry (Structure and Bonding #179)
by Markus W. RibbeThis volume highlights recent progress on the fundamental chemistry and mechanistic understanding of metallocofactors, with an emphasis on the major development in these areas from the perspective of bioinorganic chemistry. Metallocofactors are essential for all forms of life and include a variety of metals, such as iron, molybdenum, vanadium, and nickel. Structurally fascinating metallocofactors featuring these metals are present in many bacteria and mediate remarkable metabolic redox chemistry with small molecule substrates, including N2, CO, H2, and CO2. Current interest in understanding how these metallocofactors function at the atomic level is enormous, especially in the context of sustainably feeding and fueling our planet; if we can understand how these cofactors work, then there is the possibility to design synthetic catalysts that function similarly.
Metallocorroles for Attenuation of Atherosclerosis
by Adi HaberAdi Haber's thesis summarises the use of a new entity, the corrole, to combat one of the major cardiovascular diseases, atherosclerosis. She examines the effects of three rationally designed corrole-metal complexes on some of the many variables which contribute to the development of atherosclerosis. There is a focus on both the "bad" and "good" cholesterol carriers, LDL and HDL. Adi Haber proceeds from basic findings in pure chemistry through biochemical and cell culture tests to in vivo examinations. The work in this thesis shows that corroles are highly efficient both for early and late treatment of atherosclerosis in animals. These results will pave the way for ongoing regulated preclinical studies focussed on the development of metallocorroles as potential drugs for treating cardiovascular diseases.
Metalloenzymes as Inspirational Electrocatalysts for Artificial Photosynthesis
by Andreas S. J. L. BachmeierThis thesis describes a series of investigations designed to assess the value of metalloenzymes in systems for artificial and adapted photosynthesis. The research presented explores the interplay between inherent enzyme properties such as structure, rates and thermodynamics, and the properties of the semiconducting materials to which the enzyme is attached. Author, Andreas Bachmeier provides a comprehensive introduction to the interdisciplinary field of artificial photosynthesis, allowing the reader to grasp the latest approaches being investigated, from molecular systems to heterogeneous surface catalysis. Bachmeier's work also uses metalloenzymes to highlight the importance of reversible catalysts in removing the burden of poor electrocatalytic rates and efficiencies which are common characteristics for most artificial photosynthesis systems. Overall, this thesis provides newcomers and students in the field with evidence that metalloenzymes can be used to establish new directions in artificial photosynthesis research.
Metallofoldamers
by Galia Maayan Markus AlbrechtMetallofoldamers are oligomers that fold into three-dimensional structures in a controlled manner upon coordination with metal ions. Molecules in this class have shown an impressive ability to form single-handed helical structures and other three-dimensional architectures. Several metallofoldamers have been applied as sensors due to their selective folding when binding to a specific metal ion, while others show promise for applications as responsive materials on the basis of their ability to fold and unfold upon changes in the oxidation state of the coordinated metal ion, and as novel catalysts.Metallofoldamers: From Helicates to Biomimetic Architectures describes the variety of interactions between oligomers and metal species, with a focus on non-natural synthetic molecules.Topics covered include:the major classes of foldamers and their folding driving forcemetalloproteins and metalloenzymeshelicates: self-assembly, structure and applicationsabiotic metallo-DNAmetallo-PNA and iDNAmetallopeptidesinteractions of biomimetic oligomers with metal ionsapplications of metallofoldamers
Metallography in Archaeology and Art (Cultural Heritage Science)
by David A. Scott Roland SchwabThis book provides a comprehensive introduction to the metallographic study of ancient metals. Metallography is important both conceptually as a microstructural science and in terms of its application to the study of ancient and historic metals. Metallography is a well-established methodology for the characterization of the microstructure of metals, which continues to be significant today in quality control and characterization of metallic properties. Not only does the metallographic examination of ancient metals present its own challenges in terms of sample size and interpretation of evidence, but it must be integrated with archaeological data and cultural research in order to obtain the most meaningful results. Issues of authentication and the establishment of fakes and forgeries of metallic artefacts often involve metallographic evidence of both metal and patina or corrosion interface, as an essential component of such a study. The present volume sets out the basic features of relevant metallic systems, enhanced with a series of examples of typical microstructural types, with illustrative case studies and examples throughout the text derived from studies undertaken by the two authors. This book provides a comprehensive presentation of metallography for archaeologists, archaeometallurgists, conservators, conservation scientists and metallurgists of modern materials.
Metalloids in Biology: From Function to Toxicity
by Renu Bhardwaj Geetika Sirhindi Nitika Kapoor Chandra Shekhar SethMetalloids belong to class of elements that exhibit physiochemical characteristics intermediating between those of metals and non-metals. Some are quasi-essential for the overall growth and development of plants. Silicon, for instance, enhances plant structural integrity, while boron is crucial for cell wall formation, and selenium acts as an antioxidant but some are toxic, like germanium (Ge) and arsenic (As), as they threaten the soil ecosystem and human health. Metalloid toxicity hinges on their cellular concentrations ,where low levels aid plant development ,whereas high levels cause harmful effects. Thus, it is crucial to encompass the underlying detoxification mechanisms behind metalloid uptake by root system, their transport to other tissues, and their redistribution within and between cells. This book provides a comprehensive elucidation of the valuable insights of metalloids in green agriculture emphasizing management strategies to mitigate their adverse effects through various detoxification pathways, including cell complexation, cell wall binding, efflux, vacuolar sequestration and ultimately redistribution. Key features:1.Explores databases of metalloid distribution in plants and other habitats. 2.Deliberates about metalloid transporters and detoxification strategies in plants. 3. Describes interaction of metalloids with microbes and their impact on ecophysiology. 4. Unravels the mysteries of metalloid stress in plants by using multi-omics approaches. 5. Covers biological applications of metalloids in sustainable agricultural practices and in human health.This book is aimed to give updated and scientific insights to readers and researchers associated with plant stress physiology, agricultural sciences and environmentalists working for the well-being of the environment. Apart from these, the present book will also be boon for scientists, farmers, teachers and undergraduate and post graduate students as it provides a detailed account of distribution, biochemistry, detoxification mechanisms, and biological applications of metalloids.
Metalloids in Plants: Advances and Future Prospects
by Durgesh K. Tripathi Rupesh Deshmukh Gea GuerrieroUnderstanding metalloids and the potential impact they can have upon crop success or failure Metalloids have a complex relationship with plant life. Exhibiting a combination of metal and non-metal characteristics, this small group of elements – which includes boron (B), silicon (Si), germanium (Ge), arsenic (As), antimony (Sb), and tellurium (Te) – may hinder or enhance the growth and survival of crops. The causes underlying the effects that different metalloids may have upon certain plants range from genetic variance to anatomical factors, the complexities of which can pose a challenge to botanists and agriculturalists of all backgrounds. With Metalloids in Plants, a group of leading plant scientists present a complete guide to the beneficial and adverse impacts of metalloids at morphological, anatomical, biochemical, and molecular levels. Insightful analysis of data on genetic regulation helps to inform the optimization of farming, indicating how one may boost the uptake of beneficial metalloids and reduce the influence of toxic ones. Contained within this essential new text, there are: Expert analyses of the role of metalloids in plants, covering their benefits as well as their adverse effects Explanations of the physiological, biochemical, and genetic factors at play in plant uptake of metalloids Outlines of the breeding and genetic engineering techniques involved in the generation of resistant crops Written for students and professionals in the fields of agriculture, botany, molecular biology, and biotechnology, Metalloids in Plants is an invaluable overview of the relationship between crops and these unusual elements.
Metallointercalators
by Janice Aldrich-WrightA comprehensive treatment of the characterisation techniques used in investigating inorganic and organic molecules that interact with biomolecules is presented to the reader in a clear fashion. The work consists of two parts: (i) synthetic aspects of metallointercalators along with targeting and improving transport and (ii) the various techniques that are used for probing their interactions, such as; DNA-NMR, PGSE-NMR, DNA ESI-MS, Linear and Circular Dichroism, Fluorescence Spectroscopy, Confocal Microscopy, Viscosity, TGA and dialysis, Microarrays, biological analysis. Chapters are devoted to the synthesis and the techniques used to study the interactions of inorganic complexes with biomolecules. Considerably detailed examples are used to help illustrate the application of these techniques. This book is a useful resource for an array of inorganic and organic advanced undergraduate and graduate courses and for researchers in drug discovery.
Metallomics and the Cell
by Lucia BanciMetallomics and the Cell provides in an authoritative and timely manner in 16 stimulating chapters, written by 37 internationally recognized experts from 9 nations, and supported by more than 3000 references, several tables, and 110 illustrations, mostly in color, a most up-to-date view of the "metallomes" which, as defined in the "omics" world, describe the entire set of biomolecules that interact with or are affected by each metal ion. The most relevant tools for visualizing metal ions in the cell and the most suitable bioinformatic tools for browsing genomes to identify metal-binding proteins are also presented. Thus, MILS-12 is of relevance for structural and systems biology, inorganic biological chemistry, genetics, medicine, diagnostics, as well as teaching, etc.
Metallomics: Analytical Techniques and Speciation Methods
by Bernhard MichalkeLatest developments, new insights and knowledge derived from speciation analysis in one unique compilation: The reader gets acquainted with relevant instrumental as well as application aspects of metallomics approaches, paving the road to understanding fate, pathway, and action of metals in environment and organisms. Upon an introductory chapter on analytical methods and strategies, the full bandwidth of applications is discussed. Expert chapter authors cast spotlights on recent topics such as metallomics applications to environmental and nutrition studies as well as biology and medicine. Special chapters deal with the impact of manganese and iron on neurodegeneration, and the impact of nanoparticles on health.
Metallomics: The Science of Biometals (Advances in Experimental Medicine and Biology #1055)
by Marco Aurélio ArrudaThis book covers the new Omics area, Metallomics. As Metallomics is intrinsically a transdisciplinary area, this book is authored by experts in the field on such diverse topics as Environmental, Nuclear, and Human Metallomics. Within these topics metals play important role, as being part of biomolecules, controlling different biochemical process, being signaling agents, being catalyst of biochemical reactions, among others. This volume demonstrates the importance of more investigation about metals and their interactions with biomolecules. As the knowledge in this field is growing and growing daily, then new challenges concerning studies involving Metallomics is appearing, such as comparative metallomics, speciation metallomics, real-time metallomics, new predictions of metals in biomolecules, metalloprotein databank expansion, interactions between metalloprotein-metalloprotein, among others.
Metalloprotein Active Site Assembly
by Robert A. Scott Michael K. JohnsonSummarizes the essential biosynthetic pathways for assembly of metal cofactor sites in functional metalloproteins Metalloprotein Active Site Assembly focuses on the processes that have evolved to orchestrate the assembly of metal cofactor sites in functional metalloproteins. It goes beyond the simple incorporation of single metal ions in a protein framework, and includes metal cluster assembly, metal-cofactor biosynthesis and insertion, and metal-based post-translational modifications of the protein environments that are necessary for function. Several examples of each of these areas have now been identified and studied; the current volume provides the current state-of-the-art understanding of the processes involved. An excellent companion to the earlier book in this series Metals in Cells—which discussed both the positive and negative effects of cellular interactions with metals—this comprehensive book provides a diverse sampling of what is known about metalloprotein active site assembly processes. It covers all major biological transition metal components (Mn, Fe, Co, Ni, Mo), as well as the other inorganic components, metal-binding organic cofactors (e.g., heme, siroheme, cobalamin, molybdopterin), and post-translationally modified metal binding sites that make up the patchwork of evolved biological catalytic sites. The book compares and contrasts the biosynthetic assembly of active sites involving all biological metals. This has never been done before since it is a relatively new, fast-developing area of research. Metalloprotein Active Site Assembly is an ideal text for practitioners of inorganic biochemistry who are studying the biosynthetic pathways and gene clusters involved in active site assembly, and for inorganic chemists who want to apply the concepts learned to potential synthetic pathways to active site mimics.
Metalloproteins
by Juan C. Fontecilla-Camps Yvain NicoletMetalloproteins are involved in many key biological processes such as gas transport and metabolism, photosynthesis, cell respiration, the Krebs cycle and many other vital redox reactions. "Metalloproteins: Methods and Protocols" addresses multiple aspects of metalloenzyme research from the production and purification of metalloproteins using both standard recombinant techniques and a cell-free system, to the electrochemical analysis of metalloproteins, as well as IR techniques, Mossbauer spectroscopy and the theoretical interpretation of metalloenzyme catalytic and redox processes, to name a few topics. Written in the successful "Methods in Molecular Biology" series format, chapters include introductions to their respective topics, lists of the necessary materials and reagents, step-by-step, readily reproducible protocols and notes on troubleshooting and avoiding known pitfalls. Authoritative and easily accessible, "Metalloproteins: Methods and Protocols" seeks to serve both professionals and novices interested in the metalloprotein field. "
Metalloproteins: Methods and Protocols (Methods in Molecular Biology #1876)
by Yilin HuThis volume provides an up-to-date, in-depth overview of the methods that have been applied to studying the complex metalloproteins at a molecular level. Chapters cover a wide range of approaches focusing on genetic, biochemical, spectroscopic, chemical methods, and theoretical calculations. Written in the highly successful Methods in Molecular Biology series format, chapters include introductions to their respective topics, lists of the necessary materials and reagents, step-by-step, readily reproducible laboratory protocols, and tips on troubleshooting and avoiding known pitfalls. Authoritative and cutting-edge, Metalloproteins: Methods and Protocols aims to be useful for anyone who is interested in metalloprotein research and wants to address the unanswered mechanistic and biosynthetic questions of these fascinating enzyme systems.
Metalloproteins: Theory, Calculations, and Experiments
by Art E. Cho William A. Goddard IIINumerous essential biological functions involve metalloproteins; therefore, understanding metalloproteins and how to manipulate them is significant in the biological and medical fields. An examination of current research, Metalloproteins: Theory, Calculations, and Experiments explores the interplay between theory and experiment, detailing the role
Metallosurfactants: From Fundamentals to Catalytic and Biomedical Applications
by Ravneet Kaur Surinder K MehtaMetallosurfactants Provides up-to-date coverage of the synthesis, properties, and applications of metallosurfactants Metallosurfactants: From Fundamentals to Catalytic and Biomedical Applications is a thorough introduction to amphiphilic compounds that allow to incorporate metal ions in the surfactant system. This comprehensive reference and guide describes the fundamentals of metal surfactant complexes, highlights recent advances in the field, and explores current and future applications and research areas. Gradually progressing from basic to advanced topics, the authors first explain the classification and characterization of metallosurfactants before delving into more complex concepts and various catalytic, sensing, and biomedical applications. The book begins with coverage of the synthesis of metallosurfactants and their surface, interfacial, and aggregation behavior. Subsequent chapters discuss applications of metallosurfactants in areas such as drug delivery, molecular machines, transfection, nanoparticle synthesis, and carbon monoxide-releasing molecules (CORMs). Other topics include the use of metallosurfactants as catalysts in organic reactions, and as anticancer and antimicrobial agents in drug delivery and formulation. This unique reference Provides an overview of the structure-function relationship, synthesis methods, and characterization of metallosurfactants Reviews current trends in metallosurfactant development and research Examines the use of metallosurfactants in a wide range of reactions, including esterolytic reactions and hydrogen generation Discusses advanced applications of metallosurfactants, e.g. as nanoreactors for nanoparticle synthesis, non-viral transfection vectors, and sensors Metallosurfactants: From Fundamentals to Catalytic and Biomedical Applications is an excellent introduction to the growing field of metallosurfactant chemistry as well as a concise, highly useful reference for researchers and scientists in both academia and industry.